1-{Phenyl[1-(p-tolyl)ethylamino]methyl}-2-naphthol
نویسندگان
چکیده
The title compound, C(26)H(25)NO, was obtained via a one-pot synthesis from the reaction of 2-naphthol, 1-(p-tol-yl)ethyl-amine, p-toluene-sulfonic acid and benzaldehyde. There are three mol-ecules per asymmetric unit, all having similar conformations. There are intra-molecular O-H⋯N and C-H⋯O hydrogen bonds, with only van der Waals forces found between mol-ecules.
منابع مشابه
1-[(3-Methylpiperidin-1-yl)(phenyl)methyl]-2-naphthol
In the title compound, C(23)H(25)NO, the dihedral angle between the naphthyl-ene ring system and the benzene ring is 78.17 (10)°. The mol-ecular conformation is stabilized by a strong intra-molecular O-H⋯N hydrogen bond.
متن کامل1-[Morpholino(phenyl)methyl]-2-naphthol
There are two independent mol-ecules in the asymmetric unit of the title compound, C(21)H(21)NO(2), which was synthesized by the one-pot reaction of 2-naphthol, morpholine and benzaldehyde. The dihedral angles between the naphthalene ring systems and the benzene rings are 84.03 (7) and 75.76 (8)° in the two mol-ecules and an intra-molecular O-H⋯N hydrogen bond occurs in each independent mol-ecule.
متن کامل1-[(2-Methylpiperidin-1-yl)(phenyl)methyl]naphthalen-2-ol
In the title compound, C(23)H(25)NO, an intra-molecular O-H⋯N hydrogen bond defines the mol-ecular conformation; the naphthol mean plane and the benzene ring form a dihedral angle of 75.8 (2)°. The piperidine ring adopts a chair conformation. The crystal packing exhibits no short inter-molecular contacts.
متن کامل1-[Phenyl(pyridin-2-ylamino)methyl]-2-naphthol
The title compound, C(22)H(18)N(2)O, was synthesized from naphthalen-2-ol, benzaldehyde and pyridin-2-amine. In the crystal, mol-ecules are linked into centrosymmetric R(2) (2)(16) dimers by pairs of O-H⋯N hydrogen bonds. The mol-ecular conformation is stabilized by an N-H⋯O hydrogen bond. The dihedral angle between the naphthylene ring system and the phenyl ring is 72.86 (12)°.
متن کامل3-Phenyl-1-(p-tolyl)-1H-benzo[f]chromene benzene hemisolvate
The title compound, C(26)H(20)O·0.5C(6)H(6), was obtained from condensation reaction of 2-naphthol, 4-methyl-benzaldehyde and phenyl-methanamine. The naphthyl ring system is orented at dihedral angles of 84.11 (1) and 19.33 (8)° with respect to the mean planes of the two benzene rings.
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